Performance of solid oxide electrolysis cells based on scandia stabilised zirconia

Zirconia doped with scandia and ceria (10Sc1CeSZ) is presented as an electrolyte in solid oxide electrolysis cells (SOECs) for hydrogen production at intermediate temperatures. At 700 C, the conductivity of the 10Sc1CeSZ is 0.057 S cm1 and the ohmic resistance at OCV is 0.27 cm2. The electrolysis tests using Pt electrodes show that the oxygen ion conduction in the electrolyte produces high current densities when operating as a SOEC. The performance of cells with Ni-YSZ (yttria stabilised zirconia) cathodes are also tested under external potential load at temperatures between 600 C and 900 C. These preliminary results demonstrate the suitability of 10Sc1CeSZ as an electrolyte for SOECs although further work is required to develop suitable electrodes.